3.12 Antimony trioxide 124 3.12.1 Classification 124 3.12.2 Use 124 3.12.3 Legislation 126 3.12.4 Risk assessment 126 Environment 126 Human health 130 Disposal and recycling 131 3.12.5 Partial conclusion on antimony trioxide 131 3.12.6 References 132 IV Sb2O3 Antimony Trioxide is an inorganic compound predominantly utilized as a flame-retardant synergist for plastics, paints, rubber, electronics, and textiles. Prolonged or repeated contact can cause ulcers or sores in the nose. NOS Component: Antomony Trioxide Proper Shipping Name: Environmentally hazardous substances, solid, n.o.s. Substance information for UN 1561 - Arsenic trioxide based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous … Proper personal protective equipment for handling antimony trioxide include goggles, gloves and a lab coat or work garment over street clothes. SEE GLOSSARY ON PAGE 5. It is brought into this country from other countries for processing. Its TLV is 0.5 mg/m , as for most antimony compounds. Create a free website or blog at WordPress.com. Chronic exposure to antimony trioxide could result in heart or liver damage and according to the State of California, antimony trioxide is a carcinogen. In 2019, Diantimony Trioxide was selected by IARC as a medium priority substance in their 2020-2024 Monographs program. OSHA Status: Not Hazardous *The major use of (di)antimony trioxide (ATO) is as a flame retardant. 1309-64-4. Potential Chronic Health Effects: f Antimony is on the Right to Know Hazardous Substance List because it is cited by OSHA, ACGIH, DOT, NIOSH, DEP, IRIS, and EPA. Uses advised against Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Registration dossier . Hazard Summary. Air Resources Board; Three two antimony oxide is not considered hazardous chemicals transport packaging container unless over 30 pounds. Antimony Trioxide 1309-64-4 100 Toxicological Data on Ingredients: Antimony trioxide: ORAL (LD50): Acute: 7000 mg/kg [Rat]. ( Log Out /  Registration dossier . [Zimmerman, p. 4] There is evidence from pharmacologic use that antimony is nephrotoxic. : A860-100; A860-500 CAS-No 1309-64-4 Synonyms Antimony trioxide Recommended Use Laboratory chemicals. ANTIMONY TRIOXIDE Extra Pure is not on the REACH Candidate List ANTIMONY TRIOXIDE Extra Pure is not on the REACH Annex XIV List 15.1.2. Section 3: Hazards Identification Potential Acute Health Effects: Hazardous in case of skin contact (irritant, sensitizer), of eye contact (irritant), of ingestion, of inhalation. Antimony trioxide is not considered a hazardous chemical by the Department of Transportation unless packaged in containers of more than 30 pounds. Antimony Trioxide is a chemical used as a flame retardant, often in conjunction with organohalogen flame retardants[1] It is a carcinogen. If powder is inhaled, there is generally some mild irritation to the respiratory tract and the individual might experience a sore throat or cough. Antimony trioxide should not be ingested or inhaled if possible; so most manufacturing or packaging operations require their personnel to wear masks or respirators when dealing with antimony trioxide powder. This way, you can ensure that no antimony trioxide leaves the facility. FIRST AID Eye Contact f Immediately flush with large amounts of water for at least 15 minutes, lifting upper and lower lids. Antimony Trioxide TMS®-HP . ( Log Out /  Chronic Health Effects The following chronic (long-term) health effects can occur at some time after exposure to Antimony Trioxide and can last for months or years: Cancer Hazard * Antimony Trioxide may be a CARCINOGEN in humans The Oeko-Institut has recommended against a restriction of antimony trioxide (ATO) in electrical and electronic equipment under the EU’s Restriction of Hazardous Substances (RoHS) directive. They sell antimony trioxide under the names:[3] "TMS®, Timonox Red Star®, Fireshield® H, Thermoguard S / Timonox White Star®, TMS-HP®, Timonox Blue Star® Polymer Grade, Fireshield® H-HPM, Fireshield® HB, Thermoguard® HPM, Trutint® 50, Fireshield® L, Thermoguard® L, Microfine® A05, Microfine® A03, Ultrafine® II", Hazardous Substance Fact Sheet: Antimony Trioxide, Toxicity of new generation flame retardants to Daphnia magna, https://www.sourcewatch.org/index.php?title=Antimony_Trioxide&oldid=642703, Creative Commons Attribution-NonCommercial-ShareAlike, Waaijers SL, Hartmann J, Soeter AM, Helmus R, Kools SA, de Voogt P, Admiraal W, Parsons JR, Kraak MH, ". As a result, many employers provide their employees with uniforms to wear while at work and then equip their locker rooms with showers so that everyone can clean himself or herself before they leave work. List because it is a CARCINOGEN. Date of Listing: 10/01/1990. There are numerous other synonyms and product names; see the Hazardous Substances Data Bank (HSDB) for more information. Hazards of Antimony Trioxide Standard. Cases of septal perforation were reported. In February 2020, i2a provided a comprehensive set of comments on the most recent assessment of the use of antimony trioxide (ATO) in electrical and electronic equipment (EEE). Antimony trioxide. SAFETY DATA SHEET Creation Date 22-Dec-2009 Revision Date 18-Jan-2018 Revision Number 5 1. Antimony is a silvery-white metal that is found in the earth's crust. This chemical is on the Special Health Hazard Substance List because it is a CARCINOGEN." Basis for Listing: AB-IARC. … Carc. Immediate steps should be taken to limit its spread to the environment. Change ), You are commenting using your Facebook account. It is brought into this country from other countries for processing. This chemical is on the Special Health Hazard Substance Antimony Trioxide is often combined with halogenated compounds when used as a flame retardant, without antimony trioxide, about twice as much halogenated compound would be required to produce an effective flame retardant. Everyone is exposed to low levels of antimony in the environment. National regulations Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV: Is not subject of the 12. IARC In 1989, the International Agency for Research on Cancer (IARC) concluded that Diantimony Trioxide is possibly carcinogenic to humans (Group 2B), and Antimony Trisulfide is not classifiable with regards to its carcinogenicity to humans (Group 3). The assessment was performed under the EU’s Restriction of Hazardous Substances (RoHS) directive, by … Antimony trioxide (ATO) is commonly used as a cosynergist with halogenated flame retardants to enhance their effectiveness. The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries ... antimony trioxide . Antimony ores are mined and then mixed with other metals to form antimony alloys or combined with oxygen to form antimony oxide. The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. One compound — antimony trioxide — is even believed to be carcinogenic, and antimony poisoning has also been known to lead to Adams-Stokes syndrome. This condition is known in the industry as antimony measles. IARCAntimony trioxide and antimony trisulfide Some Organic Solvents, Resin Monomers and Related Compounds, Pigments and Occupational Exposures in Paint Manufacture and Painting, Vol. ATO . Usually, three oxidation two sb in 50 pounds or 25 kg bags for sale, does not conform to the standard. "[2], One manufacturer of antimony trioxide is Great Lakes Solutions, owned by Chemtura Corporation. Fill in your details below or click an icon to log in: You are commenting using your WordPress.com account. Cal EPA. The decision 2003/33/EC establishing criteria and procedures for the acceptance of waste at landfills, gives leaching limit values for Antimony from waste acceptable at landfills for inert waste. BlmSchV (Hazardous … (Antimony Trioxide) UN Number: UN3077 Hazard Class: 9 Packing Group: PG III DOT Information- 49 CFR 172.101 DOT Description: Non-Regulated By DOT in containers less than 1,041 lbs. Subjects with pre-existing conditions like heart disease or impaired respiratory function could experience more severe reactions more quickly so exposure should be limited. If for some reason antimony trioxide is ingested there can be irritation to the mouth, nose and throat as well as nausea, vomiting, bloody diarrhea, dizziness, and muscular pain. [Kanerva, p. 1753] Antimony is a "hepatotoxic agent." De tekst is beschikbaar onder de licentie Creative Commons Naamsvermelding/Gelijk delen, er kunnen aanvullende voorwaarden van toepassing zijn.Zie de gebruiksvoorwaarden voor meer informatie. However, higher concentrations have been detected at hazardous waste sites and at antimony-processing sites. [ACGIH] Antimony trioxide caused allergic contact dermatitis in two ceramics workers. Three two antimony oxide is not considered hazardous chemicals transport packaging container unless over 30 pounds. Change ), You are commenting using your Google account. A doctor’s care should be sought if ingestion occurs. Typically, antimony trioxide is sold in bags of 50 pounds or 25 kilograms, neither of which meets this criterion. Chemical Listing Details. Typically, antimony trioxide is sold in bags of 50 pounds or 25 kilograms, neither of which meets this criterion. Cancer; Listed as causing: Cancer. It is also good practice for employees to wash their skin and hair thoroughly after exposure to antimony trioxide dust. Deze pagina is voor het laatst bewerkt op 9 nov 2020 om 13:40. ( Log Out /  If the product in the sale, which can range from 1000 pounds 1000 kg, then it must be shipped… However, if you come into contact with actual antimony dust, you can experience symptoms like depression, dizziness, headaches, vomiting, kidney damage, or liver damage. Antimony ores are mined and then mixed with other metals to form antimony alloys or combined with oxygen to form antimony oxide. Wikipedia® is een geregistreerd handelsmerk van de Wikimedia Foundation, Inc., een organisatie zonder winstoogmerk. Related reading: Antimony masterbatch   Antimony ingot. Antimony is a silvery-white metal that is found in the earth's crust. Acute (short-term) exposure to antimony by inhalation in humans results in effects on the skin and eyes. AkzoNobel has decided to add antimony trioxide (ATO) to its list of restricted substances, limiting the levels permitted in the company’s products, dependent on factors such as solvent dispersion, product type and end use. 215-175-0. [Kanerva, p. 1753] Antimony is a "hepatotoxic agent." Products and Manufacturers. ( Log Out /  Three two antimony oxide is not considered hazardous chemicals transport packaging container unless over 30 pounds. Usually, three oxidation two sb in 50 pounds or 25 kg bags for sale, does not conform to the standard. This is mostly precautionary, but is good practice. However, it does not have flame retarding properties itself; instead, it is a synergist for halogenated flame retardants in plastics, paints, adhesives, sealants, rubber, and textile back-coatings. Food contains small amounts of antimony: the average concentration of antimony in meats, vegetables, and seafood is 0.2 to 1.1 parts per billion (ppb). "Exposure to Antimony Trioxide can irritate the nose, mouth, throat and lungs causing cough, wheezing and/or shortness of breath. 47, IARC Monographs on the Evaluation of Carcinogenic Risks to Humans (1989), pp. Identification Product Name Antimony(III) oxide Cat No. Change ), You are commenting using your Twitter account. We expect internal and external cables and wiring to contain levels of POPs, hazardous brominated flame retardants, antimony trioxide, plasticisers, and other chemicals above concentration limits. Antimony Trioxide is on the Hazardous Substance List because it is regulated by OSHA and cited by ACGIH, DOT, NIOSH, DEP, IARC, IRIS and EPA. While antimony will generally not harm anyone who touches it with their bare skin, some people do seem to be more sensitive to antimony trioxide. Antimony trioxide is a white crystalline solid. Antimony Trioxide may damage the kidneys, liver and heart... Antimony Trioxide is on the Hazardous Substance List because it is regulated by The primary hazard is the threat to the environment. HP7 Carcinogenic: waste which induces cancer or increases its incidence. In the EU: The decision 2000/532/EC of 3 May 2000 stipulates that Antimony Trioxide shall be classified as “heavy metal” in the classification of hazardous waste. 291-305 [Zimmerman, p. 4] See "Antimony" and linked occupational diseases. Registration dossier . OSHA and cited by ACGIH, DOT, NIOSH, DEP, IARC, IRIS and EPA. Screening assessments address potential for harm to the general population (not including workplace exposures) and the environment Chemical Status; Cancer: Currently listed. 2. Usually, three oxidation two sb in 50 pounds or 25 kg bags for sale, does not conform to the standard. Antimony trioxide is not considered a hazardous chemical by the Department of Transportation unless packaged in containers of more than 30 pounds. Antimony(III) oxide has suspected carcinogenic potential for humans. In those cases, individuals develop a rash similar to poison ivy after prolonged or repeated exposure. Antimony Trioxide can cause headaches, poor appetite, nausea, vomiting, dry throat, and loss of sleep. Antimony Oxide (Antimony trioxide) Antimony Oxide (Antimony trioxide) More information about Antimony Trioxide. or more). Little antimony is currently mined in the United States. (see above information for containers of 1,041 lbs. No other human health hazards were identified for antimony(III) oxide, and no risks to human health and the environment were identified from the production and use of antimony trioxide in daily life. Antimony: AkzoNobel restricts antimony trioxide use Posted 19th March 2020 in Industry news . People tend to be more susceptible to antimony measles when their skin is moist as when perspiring. Repeated exposure can affect the lungs and cause an abnormal chest x-ray to develop. Change ), Laminated Bag,top Laminated Bag,gloss laminated bag, Eight Advantages of Rainwater Harvesting Module from China Leiyuan, Guide for Azuregos Dragon in Nostalrius Begins, Use LED Flood Lights for Your Outdoor Lighting. Understanding PIC; ... antimony trioxide. Antimony trioxide may also be referred to as diantimony trioxide (DAT), antimony oxide, or in manufacturing as antimony white. If the product in the sale, which can range from 1000 pounds 1000 kg, then it must be shipped as dangerous chemicals and packaging group III 6.1. This page was last edited on 2 April 2014, at 07:34. Some companies that have employees who are exposed to antimony trioxide on a regular basis have each employee go through a yearly physical including chest x-rays to make sure there are no long-term adverse effects from their exposure. [IARC] Antimony trioxide caused allergic contact dermatitis in two ceramics workers. Little antimony is currently mined in the United States. It is insoluble in water. * Antimony Trioxide can cause headaches, poor appetite, nausea, vomiting, dry throat, and loss of sleep. , at 07:34 use Laboratory chemicals more than 30 pounds similar to poison ivy prolonged. Is the threat to the standard this is mostly precautionary, but is good practice de. Be limited your Facebook account antimony alloys or combined with oxygen to form antimony oxide which induces or... Details below or click an icon to Log in: You are commenting using your account! Lungs and cause an abnormal chest x-ray to develop be sought if ingestion occurs, gloves and a lab or. 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( ATO ) is commonly used as a cosynergist with halogenated flame retardants to enhance their.... Abnormal chest x-ray to develop [ ACGIH ] antimony is a `` hepatotoxic agent ''! The 12 disease or impaired respiratory function could experience more severe reactions more quickly exposure... At least 15 minutes, lifting upper and lower lids with pre-existing conditions like heart disease or respiratory... Solid, n.o.s ceramics workers antimony ores are mined and then mixed with other metals to form alloys! Name antimony ( III ) oxide Cat No and then mixed with other metals form... ( di ) antimony trioxide caused allergic contact dermatitis in two ceramics workers 2020! Organisatie zonder winstoogmerk the Evaluation of Carcinogenic Risks to humans ( 1989,... Contact dermatitis in two ceramics workers antimony in the environment nos Component: Antomony trioxide three two antimony is...: AkzoNobel restricts antimony trioxide can cause ulcers or sores in the United...., throat and lungs causing cough, wheezing and/or shortness of breath is on the Special Health Hazard Substance because. Not subject of the 12 trioxide caused allergic contact dermatitis in two ceramics workers ] There is from! Occupational diseases trioxide can cause ulcers or sores in the Industry as white! Respiratory function could experience more severe reactions more quickly so exposure should be sought if ingestion....